Hello, Tapasiya,
I'm not sure which aspect of this question you'd like help on. I'll go through the overall approach in a summary style, but please let me know if there is something for which you'd like a more thorough explanation.
I believe the equation that balances is:
2C6H6 + 15O2 = 12CO2 + 6H2O
Ugly, I know. But water's single oxygen forces us to increase the moles of water so that there are an even number of O atoms, since O only comes in as an even diatomic gas. Then the hydrogens require attention. I usually start with the most complex molecule, which would be the C6H6.
Convert the grams of both the O2 and C6H6 to moles by dividing their masses by their molar masses
O2 = 3.33 moles
C6H6 = 0.5051 moles
At first glace, one might think we have more than enough oxygen to consume all the C6H6, but we don't. The molar ratio of O2 to C6H6 is (15 moles O2)/(2 moles C6H6) or7.5. We need O2 to be 7.5 times the moles of C6H6 , or 3.788 moles O2. Oxygen is thus the limiting reagent. All of the oxygen present will consume only 0.431 moles of C6H6. (3.23/7.5).
Assuming all 0.431 moles of the C6H6 react, we can see that if we multiply that by the molar ratio of CO2/C6H6 , which is (12 moles CO2/2 moles C6H6) or 6, we will find the number of moles of CO2 produced.
6 (moles CO2/;moles C6H6)*(0.431 moles C6H6) = 2.585 moles CO2
(2.585 moles CO2)*(44g/mole CO2) = 113.7 grams CO2 (114 grams with 3 sig figs)
I hope this helps,
Bob