Hello, Jaccari,
The balanced equation tells us that 1 mole of Zn reacts with 2 moles of HCl to form 1 mole each of ZnCl2 and H2. We can state that
(1 mole ZnCl2)/(2 moles HCl)
Since we have excess zinc, we can assume all 5 moles of HCl are consumed, Now we can use the conversion factor above:
[(1 mole ZnCl2)/(2 moles HCl)]*[(6 moles HCl)] = 3 moles ZnCl2
Bob