
Sidney P. answered 03/19/21
Astronomy, Physics, Chemistry, and Math Tutor
First step is to balance the reaction, 2P + 3Cl2 --> 2PCl3. In the following I uses dimensional analysis to cancel no-longer-needed units, and I keep numbers to at least one more digit than the significant digits to avoid round-off error. Convert Cl2 mass to moles: 35.0g Cl2 *(1 mol Cl2 /70.90g Cl2) = 0.4937 mol Cl2. For every 3 moles of Cl2 gas, 2 moles of PCl3 are produced: 0.4937 mol Cl2 *(2 mol PCl3 /3 mol Cl2) = 0.3291 mol PCl3. Convert this to mass: 0.3291 mol PCl3 *(137.3g PCl3 /1 mol PCl3) = 45.19g PCl3 theoretical yield. Percent yield = 100*actual/theoretical = 4250/45.19 = 94.0% to 3 sig figs.