molarity of SCN- = moles SCN- ÷ Liters
Find the molarity, so find moles and total volume in liters:
moles of SCN-
mL to moles, using molarity:
(4.000mL NaSCN / 1 ) × (0.00200 mol NaSCN / 1000 mL NaSCN)=8.0×10-6 mol NaSCN
mol NaSCN to mol SCN-
NaSCN has just 1 SCN-, so:
1 mol NaSCN=1 mol SCN-, and
8.0×10-6 mol NaSCN=8.0×10-6 mol SCN-
Now find the total volume in Liters:
It's in a 50.0 mL volumetric flask, and
1000mL=1L, so
(50.0 mL/1)×(1L/1000mL)=0.05000 L
Molarity = (8.0×10-6 mol SCN-) ÷ 0.05000 L
Molarity = 0.000160 M, or 1.60×10-4 M