Hello, Sophia,
I just answered a similar question concerning tin ions. Please use that one to guide yiu through this nearly identical problem. This one is a little easier. Find the molar mass of As2O7. Then divide 48.9 grams by the molar mass (g/mole) to find the number of moles.
Multiply the number of moles times Avogadro's number, 6.02x1023 molecules/mole to find the number of molecules.
Bob