Robert S. answered 03/04/21
PhD in Chemistry with industrial R&D and teaching experience
Hello, Savannah,
The first problem can be solved with the ideal gas law, PV=nRT, where P is pressure, V is volume, n is moles, R is the gas constant, and T is the temperature in Kelvin.
Find the number of moles of CO2 by dividing the mass by the nmolar mass of CO2. I get 0.821 moles. I'll use the gas constant of 0.08205 L*atm/K*mole. Volume is 3.5 liters. So we have everything but pressure, which is what we can now calculate.
P = nRT/V
P = (0.821moles)*(0.08201 L*atm/K*mole)*(262K)/3.5L
After cancelling units, we are left with only atm. Perfect, I'm encouraged. Note that the temperature was converted to Kelvin.
Now take a guess at what the answer might look like, so that if there is an error in the calculation we might be alerted. 1 mole of any gas at STP occupies 22.4 liters. We have almost a mole, the temperature is higher than 273K, and we're cramming it all into a 3.5 liter container. The pressure should go up quite a bit under these conditions. Let's find out how much by rearranging the equation to isolate P:
P = nRT/V
Now enter the ata from above. I got 6.9 atm (2 sig figs), which seems high, but we did predict it would go up quite a bit just thinking about the conditions, so I'm happy.
The other 3 problems are answered in the same manner. Make a table of values for each, rearrange the equation, make a guess, and then calculate. A spreadsheet such as Excel makes these caculations easier, and you can review them afterwards and make any necessary changes more easily.
I hope this helps,
Bob