Kate R.
asked 02/15/21Naming organic compounds
I am having a little trouble naming benzoic aldehyde using IUPAC rules. It should be phenylmethanal according to outside sources, but how do I figure that out? I know that they assumed the benzene ring to be a substituent, thus the phenyl in the name, but is it like a rule that we should value naming the aldehyde as the main group and treat the benzene ring as a substituent? Couldn't it be the other way around? I found an example of a compound named methylbenzene, so here the methyl group is treated as the substituent and not the benzene ring :/
1 Expert Answer
You need to know which functional group has the highest priority. In the case of a benzene ring and aldehyde. The aldehyde has higher priority and is therefore the suffix. Since the benzene is of lower priority, it is the pre-fix. I would search "functional group priority" to find a list or check your textbook.
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Kate R.
I have the following priority list in naming: -COOH, -CHO, CO (double bond between the C and O), -OH, triple bond, double bond, halogens, alkyls. I do not know where to place benzene here... Probably between alkyls and -CHO, but unfortunately I'm clueless02/15/21