The molar ratio of hydrogen carbonate ion (HCO3-) to carbon dioxide would be 1:1. And knowing that there are 6.023 x 1023 molecules per mole (of anything),the problem could be solved as follows:
(1 mol HCO3-/1 mol CO2) (1 mol CO2/6.023 x 1023 molecules CO2) (2.25 x 1024 molecules CO2)
= 3.74 moles of HCO3-