Hi, Kevin,
The equation tells us that we should get one mole of Al2O3 for every 2 moles of Al. So if we start with 50 moles of Al, we should get 25 moles of Al2O3. We actually got 99.7 grams of Al2O3. Determine how many moles that is by dividing by the molar mass of Al2O3 (102 g/mole). Compare that to the 25 moles we should have gotten. If we got 24 moles, but expected 25, the percent yield would be (24 moles produced/25 moles expected)*(100%) = % theoretical yield.
Just looking at the numbers, it seems the percentage yield is quite low. 99.7 grams of something that has a molar mass of over 100 means we have less than a mole produced. That would be under a 1% theoretical yield. Please check the numbers you provided, or be prepared to blame it on a sloppy lab partner, if you had one.
Bob