Hello, Zoe,
The formula for ammonium phosphate is key in finding this answer. It is (NH4)3PO4. Note that each molecule of ammonium phosphate releases 3 (NH4)+ molecules when it dissolves. If we dissolve 1 mole of (NH4)3PO4, we will create 3 moles of (NH4)+ ions.
Here, we have 6.00 g of (NH4)3PO4 dissolved in 325ml of solution. Let's determine how many moles of (NH4)3PO4 are in 6.0g. We need the molar mass of (NH4)3PO4 to calculate moles of (NH4)3PO4. I get 149.1 g/mole. To find moles (NH4)3PO4, divide 6.00g/(149.1g/mole). Grams cancel and moles moves to the top, and we find we have 0.040 moles of (NH4)3PO4. That is dissolved in 325 ml of solution. The definition of concentration, Molar, is Moles/Liter. We have 0.40 moles of ammonium phosphate in 0.325 liter.
The Molarity of this solution is (0.040 Moles/0.325 L), or 0.124M (3 sig figs). The concentration of ammonium ions is thus 3*(0.124M) = 0.371M
Bob