Hello, Jack,
We need to determine the number of moles in 83.4g of KI. The molar mass of KI is 166 g/mole.
Moles KI = 83.4g KI/(166 g/mole) = 0.5024 mole KI
Concentration is Molar, and is defined as "Moles/Liter). The KI is added to 425ml of solution. We need liters, so divide by 1000ml/L, which is 0.425 L. Divide 0.5024 moles KI by 0.425L to get 1.18M KI. That is the "original concentration."
To find the concentration after dilution, use the relationship M1V1 = M2V2, where M is concentration and V is volume of the intital (1) and final (2) solutions.
M1V1 = M2V2
(1.18M KI)*(25.0ml) = M2*(125.0ml)
M2 = 0.236 M KI
Bob