Corban E. answered 01/17/21
AP Chemistry Tutor and Former Teacher (Gen Chem, High School chem)
2 mol KClO3 (3mol O2/2mol KClO3)=3 mol O2
3 mol O2 (32g/mol)=96 g O2
PV=nRT
214+273=487 K = T
P(20L)=3(0.08206)(487)
Solve for P, which is in atm due to R
P=5.9945
P=6.00 atm