Hello, Alli,
The question wants us to convert 4.58 x 1023 "formula units" into grams. Formula units can be read as "molecules." We need a conversion factor that converts molecules into grams. We'll need two, actually.
The first step is to convert molecules into moles. Avogadro's number is the information we need, since:
6.02 x 1023 molecules = 1 mole
Make this into a conversion factor by dividing one side by the other. In this case I'll divide moles by molecules:
1 = (1 mole)/(6.02x1023 molecules)
Since this is equal to 1, we can multiply it times the number of sodium sulfate molecules to yield moles sodium sulfate.
(4.58x1023 molecules Na2SO4)*(1 mole Na2SO4)/(6.02x1023 molecules Na2SO4)
The unit molecules Na2SO4 cancel, leaving moles Na2SO4.
0.761 moles Na2SO4
Then we need to convert moles Na2SO4 to grams Na2SO4. Find the molar mass of Na2SO4.
I get 142 (grams Na2SO4/mole Na2SO4)
Multiply that times the moles Na2SO4 so that moles Na2SO4 cancel, leaving grams Na2SO4.
I get 108 grams Na2SO4. Does this sound about right? Well, we can see that the number of molecules of Na2SO4 is less than the number needed to make a full mole. We also see that 1 mole should have a mass of 142 grams, so we should be under that amount, which 108 grams is.
I hope this helps,
Bob