Hello, Yoon,
We need to convert the lbs into g. 1lb = 453.6g, so we have 376.5 grams of Na2CrO4. Find the molecular weight of sodium chromate, which I calculate to be 262 g/mole. By dividing the mass by the molar mass, we get the number of moles (= 1.44 moles Na2CrO4). This is dissolved in 3567 ml water. Convert this to Liters (=3.567 L) and then divide that into the moles to gives us moles/Liter, or Molar. I get 0.403M.
If we take 15 ml of a 0.403 M solution, we can calculate the number of moles of the solute. But note that Molar is (moles/liter), so we need to convert to 15ml into Liters (=0.015). Multiply the two (M x Vol in L) to give the moles present in 15ml (= 0.00604 moles). Since one mole = 6.022x1023, multiply this number times the number of moles to get the number of Na2CrO4 molecules.
Be careful with sig figs. I see only two in the 0.83 number.
Bob