Anya L.

asked • 12/04/20

What is the pH of a 0.075 M LiOH solution?

What is the pH of a 0.075 M LiOH solution?


1 Expert Answer

By:

Greg S. answered • 12/04/20

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Science & Math Tutoring from a Scientist (MIT SB, NU PhD)

J.R. S.

tutor
I think you meant that pOH is -log [OH-], and pH = pOH = 14.
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12/04/20

Greg S.

Absolutely correct, JRS. Thank you. pH will be 14 - pOH, and the pOH is -log([OH-]). Quite right. Did you happen to notice my answer to the question you addressed with the Henderson Hasselbach equation? Unless I'm (again) mistaken, you can't use the small-dissociation approximation there...
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12/04/20

J.R. S.

tutor
I had not noticed your answer until just now, and I agree with you because of the strength of the "weak" acid H3PO4. The Ka is considerably greater than most other weak acids. This, of course, accounts for the significant dissociation, and you are quite correct that one should not use the approximation that I used. Thanks for the follow-up.
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12/04/20

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