Anthony T. answered 11/20/20
I googled to find the heat of combustion of methanol and found it to be -715 kJ/mol. Inverting this number, you get 1/-7.15 mol/kJ. Multiply by the 995 kJ in the problem to get the number of moles needed to get that much heat evolved. This turns out to be 139.2 moles.
As the molecular weight of methanol is close to 32 g/mol, the number of grams is
32 g/mol x 139.2 mols = 4450 g to 3 sig figs.