Corban E. answered 11/18/20
AP Chemistry Tutor and Former Teacher (Gen Chem, High School chem)
Ge is larger, Br is smaller
Simple explanation: Radius increases moving down a family, and to the left.
More detailed explanation:
Coulomb's law
Force=(charge magnitude)/distance between charges
F=(Q1Q2)/d
F=force between charges
Q1Q2=magnitude of charge (+-1, +-2, +-3, etc. bigger numbers=stronger force)
d=distance between charges. smaller distance=stronger force
Consider Ge and Br
Ge:
- 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^2
- 32 protons
Br:
- 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^5
- 35 protons
For Br, there are more p+’s in the nucleus (Q1Q2 increases), but e–‘s are in the same shell (4s, 4p, distance is constant). The force increases, so the nucleus pulls the valence e–‘s “in” more strongly to decrease the radius.