Zehra H. answered 11/19/20
MCAT tutor 98 percentile score, BA Biochemistry, Med School Graduate
Corner atoms count as 1/8 each (only 1/8 of them is inside the boundaries of the unit cell)
Center/Body atoms count as 1 whole (whole thing inside the unit cell)
Face atoms count as 1/2 each (they're half in, half outside the unit cell)
(FYI edge atoms count as 1/4)
So for anions, the calculation is
1/8 anion at each corner x 8 corners on a cube = 1 anion
+ 1 whole anion
= 2 anions per cell
For cations, the calculation is
1/2 cation at each face x 6 faces on a cube = 3 cations per cell
The unit cell contains a net 3 cations and 2 anions.