Jon P. answered 02/13/15
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Call the width w.
The dimensions of the painting and the frame are 10 + 2w by 14 + 2w. It's 2w in both cases because the frame is on both the top and the bottom, and the left and the right, of the painting.
The perimeter is 2(10 + 2w) + 2(14 + 2w) = 20 + 4w + 28 + 4w = 48 + 8w.
We know that's equal to 64 inches, so that gives us an equation:
48 + 8w = 64
8w = 16
w = 2 inches