The Voltage will remain constant and the capacitance will change. The energy is 1/2CV2. Therefore, if we find the new Capacitance, C', then E'/E = C'/C because the energy is proportional to the capacitance for the same voltage.
The capacitance is related to the κ (dielectric constant), A (Area) and d (distance between the plates by the formula: C = κε0A/d
C'/C = (κ'/κ)(d/d') = 3.3*2 = 6.6 because the capacitance is proportional to the dielectric constant and inverse with the distance between the plates. (A kept constant)
Therefore E'/E = 6.6 or E' = 6.6 x 10-4 J