
Morgan S. answered 07/23/20
Expert in General Chemistry Topics
To answer this question, let's first look at the atoms in the compounds for which we know the oxidation number. Oxygen has an oxidation number of 2-. So, in SO3, in order to create a net neutral, or zero charge, the S must have an oxidation number 6+ to cancel out the 3*(-2)= -6 of the oxygen in the compound.
Hydrogen has an oxidation number of 1+. In H2SO4, the hydrogen atoms create 2*(+1) charge and the oxygen atoms create 4*(-2) charge. The S must have an oxidation number of 6+ that will cancel out these charges, 2*(+1) + 4*(-2) = -6.