Hello Rafael:
In this problem, we need the Avogadro's number, which states that the number of representative particles contained in one mole of a substance equal to 6.02 x 1023 particles. In this case: atoms. From the periodic table, the atomic mass of As is 74.922.
First, we calculate the number of moles of As equivalent to 35.7 grams as follows:
mole As = gram As x 1 mole/Atomic mass As
mole As = 35.7g x 1 mole/74.92 g = 0.4765 mole
Number of atoms in 0.4765 mole As = 0.4765 mole x 6.02 * 1023 atoms/1 mole
= 2.87 * 1023 atoms
Therefore, the number of As atoms in the 35.7 gram sample of As is 2.87 x 1023.