
Chris C. answered 04/22/20
Enjoying (??) Chemistry ... yes, REALLY!!
Hi, Aaron,
The empirical formula for any compound is the lowest whole number ratio of atoms in a given compound. So, let's look at your three molecular formulas:
1) C6H12O22 - for any compound, to determine the empirical formula, start by dividing each elements "quantity" by the smallest formula value. In this case, that number is 6 (which is the smallest of 6, 12, and 22), so we obtain: C6 ÷ 6 = C1
H12 ÷ 6 = H2
and O22 ÷ 6 = O3.67
But, remember, an empirical formula is only valid with whole number ratios ... and 3.67 isn't a whole number!! To fix this, it is helpful to recognize that 3.67 is also 3 2/3, which is the same as 11/3. If we multiply each of those above values by 3, we'll obtain C3H6O11, which is the empirical formula for this compound.
2) Fe2O3: if we even start to divide 2 by 2 and then 3 by 2, we'll quickly see that we have already violated our whole number rule for empirical formulas. In this example, the empirical formula for Fe2O3 is Fe2O3!
3) C2H2 ... now that you've seen the first examples, do you think you can do this one, Aaron? I'm thinking you can, so I'll leave this for you "to" work out (oh, major hint there!).
Good luck,
Chris