If you are to draw the Lewis dot structures for each of the mentioned compounds you'd find the following geometries.
SiSe2 would be linear thus non-polar.
SI4 Sulfur being able to expand its octet would take on a seesaw geometry and would be polar.
XeF4 Xenon also able to expand its octet would take on a square planar geometry and would be non-polar.
CCl4 This molecule would take on a tetrahedral geometry and would be non-polar.
Thus one of the listed molecules are polar.
I hope this helps!