
Chris C. answered 04/17/20
Enjoying (??) Chemistry ... yes, REALLY!!
Hi, Noah,
A great question!! So, this is an application of Avogadro's law (which is derived from the ideal gas law or PV = nRT where P is the gas pressure, V is the volume occupied by the gas, n is the moles of gas, R is the ideal gas constant, and T is the temperature in Kelvin). Assuming no change in pressure or in temperature reduces this problem to
, where k is a constant for any given temperature and pressure.
In this case, since the volume and molar quantity of the gas are changing, you need to solve the following equation:
So, for this particular problem:
0.8323 L = 4.266 L
n1 20.4 mol, or n1 = (20.4)(0.8323) ÷ 4.266,
or n1 = 3.98 mol of helium initially.