Dr. DJ W. answered 08/11/20
Highly Experienced Chemistry Tutor|UCLA PhD Scientist|10+ yrs|
First you need the balanced Equation as below:
CS2 (s) + 4 Cl2 (g) → CCl4 (l) + 2 SCl2 (s)
You may start with any of the reactants and calculate how much of the other reactant you need to react with the given amount.
Let's start with CS2: We have 27.3g of CS2
we can calculate how many grams of Cl2 we need to react with that 27.3g of CS2 as below in one step:
27.3g of CS2 (1 mol CS2/76.14g CS2) x (4 mol Cl2/1molCS2) x (70.9g Cl2/1mol Cl2) = 102g Cl2
Therefore we need only 102g of Chlorine gas, as we have more than enough (129g), Chlorine gas will be the excess reagent and CS2 will be the limiting reagent.
Therefore we can calculate how much CCl4 can be formed ONLY starting with our limiting reagent, CS2: as below;
27.3g of CS2 (1 mol CS2/76.14g CS2) x (1mol CCl4/1molCS2) x (153.8g CCl4/1mol CCl4) = 55.1g CCl4
Note that you can always only use the limiting reagent for the calculations of product amounts, as it is the only reagent that'll get 100% consumed/reacted.
