
William W. answered 03/09/20
Math and science made easy - learn from a retired engineer
The process you describe has 5 separate pieces as shown in the graph below:
Section A is the heating of the solid ice from -35 to zero.
Section B is the phase change of solid ice to liquid water.
Section C is the heating of liquid water from zero to 100.
Section D is the phase change from liquid water to gaseous steam
Section E is the heating of steam from 100 to 185.
Section A: We use the equation Q = mCiΔT where Ci is the specific heat of ice (2.06 j/(g°C) and ΔT = 35 °C
So Q = (12)(2.06)(35) = 865.2 joules
Section B: We use Q = mΔHf where ΔHf is the heat of fusion or the heat required to accomplish the phase change of ice to water (334.16 J/g). So Q = (12)(334.16) = 4009.92 joules.
Section C: Again we use the equation Q = mCwΔT but this time Cw is the specific heat of liquid water (4.184 j/(g°C) and ΔT = 100 °C
So Q = (12)(4.184)(100) = 5020.8 joules
Section D: Again we use Q = mΔHv where ΔHv is the heat of vaporization or the heat required to accomplish the phase change of water to steam (2259 J/g). So Q = (12)(2259) = 27108 joules.
Section E: Again we use the equation Q = mCSΔT but this time CS is the specific heat of steam (2.02 j/(g°C) and ΔT = 85 °C
So Q = (12)(2.02)(85) = 2060.4 joules
So the total heat required is 865.2 + 4009.92 + 5020.8 + 27108 + 2060.4 = 39064.32 joules. Converting to kCal we get (39064.32 joules)(0.000239006 kcal/1 joule) = 9.34 kcal