
Jim L. answered 07/11/19
Personable, effective English, Math and Science Tutor
You need to use mole-matching here. 21.1 mL of a .0203 M solution of KMnO4 yields (.0211*.0203) moles or .000428 moles of potassium permanganate.
The balanced equations says that 2 moles of potassium permanganate needs 5 moles of oxalic acid to titrate to the endpoint. So we need 5*.000428/2 = 0.00107 moles. of H2C2O4
We want to find the concentration of oxalic acid where 0.00107 = M*.025L .
So M = .00107/,025 = 0.0428 M/L