Allen S. answered 01/07/15
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Sodium bisulfate chemical formula is NaHSO4 :
In this form Na is the cation of Na+ and HSO4 is the anion HSO4- :
Almost every time you have a cation and anion form a compound, it is considered ionic, especially if the resulting compound is considered a salt, which NaHSO4 certainly is.
The shape of the molecule is tetrahedral:
The bonds in HSO4 are:
Double covalent bond between the sulfur atom and 2 of the oxygen atoms:
Single covalent bond between the sulfur atom and an oxygen atom with - charge
Single covalent bond between the sulfur atom and the hydroxyl group (HO)
Adding the Na+ cation to the mix forms an ionic bond with the O- atom on one of the legs