Mark O. answered 05/24/19
Experienced and Very Knowledgeable Theoretical Physicist
PV1.4 = k
Differentiate with respect to time. P and V are both functions of time, and so you need to use the product rule from Differential Calculus.
(dP/dt)V1.4 + 1.4PV0.4(dV/dt) = 0 The right-hand side is 0 since k is a constant.
At some instant, we are told that P = 40 atm, V = 28 L, dV/dt = -2.0 L/min where the negative sign because volume is decreasing in time. We do not know dP/dt, and we are being asked to find this.
Rearrange the last differential equation.
(dP/dt)V1.4 = -1.4PV0.4(dV/dt)
Multiply through by V-1.4.
dP/dt = -1.4PV-1(dV/dt)
dP/dt = -1.4(P/V)(dV/dt)
dP/dt = -1.4(40 atm / 28 L)(-2.0 L/min)
dP/dt = 4.0 atm / min