Aligning timestamps can be a common need, particularly when shooting with more than one camera and/or a second shooter/friend/family member despite best efforts to keep the cameras' clocks synchronized.
Thankfully, there's a solution in the library module. Go the metadata menu and select "Edit Capture Time.." A dialog box will guide you through the process.
You can batch process the changes by first selecting all the images that need to be shifted by the same amount. Input the correct date and time for the first image, and all the selected images will be shifted accordingly.