You would use Dalton's Law of Partial Pressures to determine the pressure of the Ne. In order to do this, you need a table showing the vapor pressure of water at various temps. The table I have show that the Pvap of H2O at 27oC = 26.74 mmHg
So,
PT = PNe + PH2O
753.4 mm Hg = PNe + 26.74 mm Hg
Solve for PNe