J.R. S. answered 05/11/18
Tutor
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Ph.D. in Biochemistry--University Professor--Chemistry Tutor
You can't really use M1V1 = M2V2 to find MOLES. You can use that formula to find moles/liter, or molarity (M).
In this problem, the fact that the original solution is diluted doesn't really matter. The number of moles of CaCl2 is determined only by the volume of the 3.0 M solution that is used. Whether it is diluted to 750 ml or 7500 ml, doesn't change the number of moles in the final solution. Thus....
250 ml = 0.250 L
0.250 L x 3.0 moles/L = 0.75 moles CaCl2
Now, if you wanted to solve for the MOLARITY of the final solution, then you could use M1V1 = M2V2, and that answer would be (250 ml)(3.0 M) = (750 ml)(x M) and x = 1.0 M