
John B.
asked 04/25/18Hess's Law Problem. PLEASE HELP
Use Hess’s Law to calculate the enthalpy of combustion for ethane gas, C2H6 given the following data:
C2H4 (g) + 3 O2 (g) → 2 CO2 (g) + 2 H2O (g) ΔH = -1323 kJ/mole
C2H4 (g) + H2 (g) → C2H6 (g) ΔH = -137 kJ/mole
for H2O (g) ΔHOf = -241.8 kJ/mole
H2O (l) → H2O (g) ΔH = +44
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1 Expert Answer
J.R. S. answered 04/26/18
Tutor
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Ph.D. University Professor with 10+ years Tutoring Experience
2C2H6 + 7O2 ==> 4CO2 +6H2O This is the equation for combustion of ethane
Reverse the second equation and multiply by 2:
2C2H6 ==> 2C2H4 + 2H2 ∆H = 2x-137 = -274 kJ
Multiply first equation by 2:
2C2H4 + 6O2 ==> 4CO2 + 4H2O ∆H = 2x-1323 = -2646 kJ
Add these 2 together to get:
2C2H6 + 2C2H4 + 6O2 ==> 2C2H4 + 2H2 + 4CO2 + 4H2O ∆H = -2929 kJ
C2H4 cancel leaving 2C2H6 + 6O2 ==> 4CO2 + 4H2O + 2H2
Note that we need an additional O on the left and we need to cancel 2H2 on the right.
Using H2 + 1/2O2 ==> H2O ∆H = -241.8 kJ. Multiply this by 2 and add it to the final equation above:
2C2H6 + 6O2 ==> 4CO2 + 4H2O + 2H2 ∆H = -2929 kJ
2H2 + O2 ==> 2H2O ∆H = 2x-241.8 = -483.6
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2C2H6 + 7O2 ==> 4CO2 + 6H2O ∆H = -483.6 + -2929 = -3412.6 kJ
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J.R. S.
04/26/18