Start with what you have and work to what you want. The deadly dose would be 5g dioxin/1000000000g body mass.
500g dioxin x 1 human/70kg body mass x 1kg/1000g x 1000000000g body mass/5g dioxin= 1428571.4 humans.
So 500g dioxin could theoretically kill 1,428,571 people.