J.R. S. answered 12/18/17
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2C2H4O2(aq) + CaCO3(s) ==> Ca(C2H3O2)2(aq) + CO2(g) + H2O(l)
The acetic acid is a weak acid and it reacts with the insoluble calcium carbonate to form the soluble calcium acetate and carbonic acid. The carbonic acid is unstable and decomposes into carbon dioxide and water.