J.R. S. answered 11/13/17
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Ph.D. in Biochemistry--University Professor--Chemistry Tutor
They are all ionic compounds, and have a positive and negative attraction (coulombic force). However, all of the halogens are NOT the same SIZE. And it is here that SIZE MATTERS. F is the smallest of the halogens, and thus the packing of the lattice structure is "tighter", and so it takes more energy to break the lattice. This explains why NaF has a higher melting point than, say NaCl, etc.