1) I'm going to assume that you meant 225g of CO2, not NO2. If you meant NO2 both times, the procedure will be the same (although the numbers will be different). Note from your periodic table that C has an atomic mass of 12 and Oxygen has an atomic mass of 16. Therefore, CO2 has an atomic mass of 12+2(16) = 44. That means there are 44 g CO2 / mol CO2. So, we can run this one like a unit conversion problem:
225 g CO2 * (1 mol CO2 / 44 g CO2) = 5.11 mol CO2
2) Atomic masses:
K: 39
Cr: 52
O: 16
K2Cr2O7: 2(39) + 2(52) + 7(16) = 294
3.50 mols K2Cr2O7 * (294 g K2Cr2O7 / 1 mol K2Cr2O7) = 1030 g K2Cr2O7