Gram Molecular Weight of Na = 23
O = 16
H = 1
C = 12
Therefore, Gram Molecular Weight of NaOH = 23+16+1 = 40
7.11 g / 40 g = 0.17775 moles of NaOH
0.17775 m / 8.33 L = 0.02134 moles / liter
Concentration of solution is 0.02134 M
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In order to make 3.75 L of 0.075 mol/L solution, you need 3.75 * 0.075 or 0.28125 moles
Gram molecular weight of NaHCO3 = 23+1+12+16*3 = 84
0.28125 moles of NaHCO3 is 0.28125 * 84 = 23.625 grams