1) Find Weight of 3.54 moles of NH4Cl in 100 mL of solution.
Mass=Moles*Molar Mass or 53.50*3.54 or 189.39 grams.
grams NH4Cl per mL= 189.39 g/1000 mL or 0.18939 g/mL
mass% NH4Cl=(mass of NH4Cl/Mass of solution)*100%
mass% NH4Cl=(0.18939/1.0512)*100% or 18.02% or 18%