1.
Total pressure=vapor pressure of water + gas pressure of sample.
425 torr=oxygen pressure + 22.377 torr
402.62 torr=gas pressure of oxygen.
Turn torr into atm: 402.62 torr*(1 atm/760 torr) or 0.52976 atm
Use PV=nRT equation to find mass of oxygen (solve for n)
P=0.52976 atm, V=1.335 L, T=273.15 + 24 K or 297.15 K, n=?
n=(PV)/(RT) or (0.52976atm*1.335L)/(0.08206 L-atm/mol-K*297.15K)
n=0.029 mole
2.
At STP, P=1 atm, T=273.15 K, V=?
Volume=Volume of Oxygen Gas + Volume of Argon Gas
V=(nRT)/P
moles of Oxygen=129 g/31.999 g per mole or 4.03 moles O2 gas.
moles of Argon=24 g/15.7596 g per mole or 1.52 moles Ar gas.
add moles together and plug into formula V=nRT/P
Volume=(4.03 + 1.52 moles)*(0.08206 L-atm/mole-K)*273.15 K/1 atm
Volume=124.4 mL