
Scott B. answered 04/14/22
PhD in physics with one year experience as a professor
Lets' derive it from the start.
For exponentially decaying quantities (like the number of atoms in a sample of some radioactive isotope), the following differential equation applies
dy/dt= - ky
where k is some constant and y is the amount of sample at time t. This can be solved by simple separation of variables, and you end up with
dy/dt= - ky
dy/y=-kdt
Ln(y(t))=-kt+c
y(t)=exp(-kt+c)
y(t)=exp(c)*exp(-kt)
y(0)=exp(c)=y0
y(t)=y0exp(-k*t)
where y0 is the initial quantity of atoms in your sample. This equation is general, and can be applied to any decaying isotope; all that changes are the amount in your initial sample and the decay constant k (k being an intrinsic quantity of that isotope; different isotopes have different ks, but two samples of the same isotope will have the same k).
The half-life of an element is defined as the time required for half of the sample to decay. So, at time t=t1/2, we have
y(t1/2)=y0exp(-k*t1/2)=1/2 y0
We can solve this for k, allowing us to express k in terms of the half-life:
y0exp(-k*t1/2)=1/2 y0
exp(-k*t1/2)=1/2
-k*t1/2=Ln(1/2)
-k*t1/2= - Ln(2)
k*t1/2=Ln(2)
k=Ln(2) / t1/2
So, that's how k depends on the half-life. Remember, this expression is the same for the decay of any isotope of any element; all that changes is the half-life.
So, now for the punchline. Since k depends inversely on the half-life, increasing the half-life reduces the decay constant, since you're dividing by a larger number! That's really all you need, but you could be explicit and substitute the numbers.
krad-226=Ln(2)/1600=0.000433217 yr-1
kcar-14 =Ln(2)/5730=0.000120968 yr-1