Use Snell's Law.
n1sin(θ1) = n2sin(θ2)
Since medium 1 is air, n1 = 1, and it is given that n2 = 1.53. It is also given that θ2 = θ1/2. So we have the following.
sin(θ1) = 1.53sin(θ1/2)
Here's the trick: Use the Double Angle Formula for the sine function on the left side.
2sin(θ1/2)cos(θ1/2) = 1.53sin(θ1/2)
Cancel the factor of sin(θ1/2) on both sides.
2cos(θ1/2) = 1.53
cos(θ1/2) = 1.53/2 = 0.765
θ1/2 = cos-1(0.765) = 40.1ο
θ1 = 80.2ο