You need to look at the geometry of the situation. In the third phase of the moon the sun and the earth will be exerting forces at right angles. As a result you can get the magnitude of the total force by taking the pythagorean sum of the forces F = sqrt(FS2 + FE2). The direction will be a little trickier as you have to establish the angle you are talking about. If the sun is a 0 degrees and the earth at 90 degrees, then the angle from the direction of the sun will be arctan(FE./FS) . If the sun is to the left at -180, just subtract 180 from the last solution.
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