I assume the circle is inscribed within the square; that is, it just touches each side of the square. In that case, the circle's radius is (1/2)*(20) = 10 cm. The area of the circle is:
AC = pi*radius2 = (3.14)*(102) = 314 cm2
The area of the square is:
AS = (side)2 = 202 = 400 cm2
The probability that a dart will land within the circle (if it lands within the square) is:
AC/AS = 314/400 = 0.785