
Stanton D. answered 07/21/20
Tutor to Pique Your Sciences Interest
Hi Noodles D.,
As you probably already know(?), you start with Snell's Law : n1sinθ1 = n2sinθ2 . To have total internal relection, you need sinθ2 > 1 (so that the exit ray would have to be refracted to *lower* than the surface). That will occur with the right combination of sinθ1 and n1/n2 . In particular, it can only happen on passage from a higher to a lower index of refraction. Look up your indices of refraction, and start calculating (anything to a vacuum can have T.I.R., since vacuum has n=1).
Strangely enough, the light which will be totally internally reflected, "samples" the medium it does not totally emerge into. If there is something there which absorbs certain frequencies of light, some of those frequencies can be at least partially absorbed, and therefore be weaker or missing in the totally internally reflected light beam.
This can also happen with ordinary reflected light, i.e. reflected light from a solid. That's the reason that the metal gold is yellow colored: the reflected light "samples" into the metal, and the blue portions are absorbed. (in thin layers of gold, which are thicker than the zone sampled by reflected light, more of the spectrum is absorbed, and the transmitted light color is red).
-- Cheers, --Mr. d.