The critical points are found by finding the x-values for which the derivative equals zero or for which the derivative does not exist.
This function is in the form of u•v where u = x and v = e-2x. (two functions multiplied together) and so to find the derivative, we must use the product rule that says where (in this case) g(x) = u•v then g'(x) = u'v + uv'
So, since u = x, then u' = 1 and since v = e-2x, v' = -2e-2x (by the chain rule)
So:
g'(x) = u'v + uv'
g'(x) = (1)(e-2x) + (x)(-2e-2x)
g'(x) = e-2x - 2xe-2x
g'(x) = e-2x(1 - 2x)
This function exists for all values of x, so we just need to find where it is equal to zero. Using the zero product rule, for g'(x) to be equal to zero, then either e-2x = 0 or 1 - 2x = 0. e-2x can never be zero, so we only need to find when 1 - 2x = 0
1 - 2x = 0
1 = 2x
x = 1/2
So the only critical point is x = 1/2
Since we are also looking for the points of inflection, we will need to take the second derivative so I'll wait to determine if x = 1/2 is a max or min by looking at the second derivative.
To find g'', since g'(x) = e-2x(1 - 2x) we also will need to use the product rule, this time u = e-2x and v = 1 - 2x
So u' = -2e-2x and v' = -2
g''(x) = u'v + uv'
g''(x) = (-2e-2x)(1 - 2x) + (e-2x)(-2)
g''(x) = -2e-2x + 4xe-2x - 2e-2x
g''(x) = -4e-2x + 4xe-2x
g''(x) = 4e-2x(x - 1)
Again, setting this to zero gives us only x - 1 = 0 or x = 1 as a POSSIBLE point of inflection. To check, let's perform the 2nd derivative test.
We draw a number line and put the critical point and the possible point of inflection on it:

And then we evaluate the sign of g'' in the various intervals shown, like this:

So, x = 0.5 must be a relative maximum (since it is concave down on the interval surrounding it. And there is a point of inflection at x = 1 because it changes concavity there.