Since the parabolic path is symmetric above & below the 45 degree angle, the distance from the 45 degree to 68 degrees is 23 degrees.
45 -23 = 22 degrees. So if you throw the snowball at 22 degrees, it would go the same distance (84.8 m).
However, you would throw the second snowball later (6.54-2.643) = 3.9 seconds later to have the snowballs hit at the same time!