Let the coordinate going down the ramp is x so positive x is down the ramp.
Let the weight of the block= mg
Let N = Normal force acting on the block from the ramp
Let u = the coefficient of friction = .9
Let a = the angle of the ramp
The forces on the block in the x direction is mgsin(a) - uN = 0 = mgsin(a) - umgcos(a) (In equilibrium)
Simplifying, sin(a) = ucos(a) or u = sin(a)/cos(a) = tan(a) = .9
Therefore, a = 41.99 degrees
So, at any angle above 41.99 degrees, the block will start to move