Two angles, say θ and φ, are supplementary if their sum is 180o. That is:
θ + φ = 180o
So if you know one of the angles, say θ, you can find the other (φ) as follows:
φ = 180o - θ
For problem (a), you need to remember that 1 degree = 60 minutes, and one minute = 60 seconds, so 180o = 179o 59' 60"
179o 59' 60"
-46o 59' 37"
--------------
133o 0' 23"
Can you do (b)?